好評の新刊 Dennis Hall編 Boronic Acids 第2版 - 豪華な執筆陣にもご注目下さい

昨年10月に出版され、全2巻・700頁以上の大著にもかかわらず大好評をいただいている本をご紹介します。
Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials, Second, Completely Revised Edition, 2 Volume Set
Dennis G. Hall (Editor)
ISBN: 978-3-527-32598-6
Hardcover / 726 pages / October 2011

本書は、鈴木-宮浦カップリングをはじめ有機化学で広く用いられるボロン酸について、最新の幅広い知見をまとめたものです。大成功を収めた旧版(2005年)を基に、内容の約50%を刷新した大幅改訂版です。ボロン酸に関する大家Dennis Hallを編者に、鈴木 章先生から序文を、また山本 尚先生、宮浦 憲夫先生、林 民生先生らをはじめ世界各国の優れた研究者から寄稿を得た本書は、当分野で必須の参考図書といえます。

- 本書の目次 -

1 Structure, Properties, and Preparation of Boronic Acid Derivatives: Overview of Their Reactions and Applications
 Dennis G. Hall
 1.1 Introduction and Historical Background
 1.2 Structure and Properties of Boronic Acid Derivatives
 1.3 Preparation of Boronic Acids and Their Esters
 1.4 Isolation and Characterization
 1.5 Overview of the Reactions of Boronic Acid Derivatives
 1.6 Overview of Other Applications of Boronic Acid Derivatives

2 Metal-Catalyzed Borylation of C–H and C–Halogen Bonds of Alkanes, Alkenes, and Arenes for the Synthesis of Boronic Esters
 Tatsuo Ishiyama and Norio Miyaura
 2.1 Introduction
 2.2 Borylation of Halides and Triflates via Coupling of H–B and B–B Compounds
 2.3 Borylation via C–H Activation
 2.4 Catalytic Cycle
 2.5 Summary

3 Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds
 Michinori Suginome and Toshimichi Ohmura
 3.1 Introduction
 3.2 Diboratio
 3.3 Silaboration
 3.4 Carboboration
 3.5 Miscellaneous Element-Boryl Additions
 3.6 Conclusion

4 The Contemporary Suzuki–Miyaura Reaction
 Cory Valente and Michael G. Organ
 4.1 Introduction
 4.2 Developments Made in the Coupling of Nontrivial Substrates
 4.3 Asymmetric Suzuki–Miyaura Cross-Couplings
 4.4 Iterative Suzuki–Miyaura Cross-Couplings
 4.5 Conclusions and Future Outlook

5 Rhodium- and Palladium-Catalyzed Asymmetric Conjugate Additions of Organoboronic Acids
 Guillaume Berthon-Gelloz and Tamio Hayashi
 5.1 Introduction
 5.2 Rh-Catalyzed Enantioselective Conjugate Addition of Organoboron Reagents
 5.3 Pd-Catalyzed Enantioselective Conjugate Addition of Organoboron Reagents
 5.4 Conclusions

6 Recent Advances in Chan–Lam Coupling Reaction: Copper-Promoted C–Heteroatom Bond Cross-Coupling Reactions with Boronic Acids and Derivatives
 Jennifer X. Qiao and Patrick Y.S. Lam
 6.1 General Introduction
 6.2 C–O Cross-Coupling with Arylboronic Acids
 6.3 C–N Cross-Coupling with Arylboronic Acids
 6.4 Substrate Selectivity and Reactivity in Chan–Lam Cross-Coupling Reaction
 6.5 C–N and C–O Cross-Coupling with Alkenylboronic Acids
 6.6 C–N and C–O Cross-Coupling with Boronic Acid Derivatives
 6.7 C–S and C–Se/C–Te Cross-Coupling
 6.8 Mechanistic Considerations
 6.9 Other Organometalloids
 6.10 Conclusion
 6.11 Note Added in Proof

7 Transition Metal-Catalyzed Desulfitative Coupling of Thioorganic Compounds with Boronic Acids
 Ethel C. Garnier-Amblard and Lanny S. Liebeskind
 7.1 General Introduction
 7.2 Boronic Acid-Thioorganic C–S Desulfitative Cross-Couplings Using Catalytic Nickel or Palladium
 7.3 Thioorganic C–S Desulfitative Cross-Couplings Using Only Catalytic Copper
 7.4 Miscellaneous
 7.5 Conclusions

8 Catalytic Additions of Allylic Boronates to Carbonyl and Imine Derivatives
 Tim G. Elford and Dennis G. Hall
 8.1 Introduction
 8.2 Additions to Aldehydes
 8.3 Additions to Ketones
 8.4 Additions to Imine Derivatives
 8.5 Conclusions

9 Recent Advances in Nucleophilic Addition Reactions of Organoboronic Acids and Their Derivatives to Unsaturated C–N Functionalities
 Timothy R. Ramadhar and Robert A. Batey
 9.1 Introduction
 9.2 Recent Advances in the Petasis Borono-Mannich Reaction
 9.3 Reactions of N-Acyliminium Ions with Organoboronic Acids and Their Derivatives
 9.4 Advances in Metal-Catalyzed Additions with Organoboronic Acids and Their Derivatives
 9.5 Conclusions

10 Asymmetric Homologation of Boronic Esters with Lithiated Carbamates, Epoxides, and Aziridines
 Matthew P. Webster and Varinder K. Aggarwal
 10.1 Introduction
 10.2 Lithiated Primary Alkyl Carbamates for the Homologation of Boranes and Boronic Esters
 10.3 Lithiated Secondary Carbamates for the Homologation of Boranes and Boronic Esters
 10.4 Benzylic N-Linked Lithiated Carbamates for the Homologation of Trialkylboranes
 10.5 Lithiated Epoxides for the Homologation of Boronic Esters
 10.6 Lithiated Aziridines for the Homologation of Boronic Esters
 10.7 Conclusions

11 Organotrifluoroborates: Organoboron Reagents for the Twenty-First Century
 Gary A. Molander and Ludivine Jean-Gérard
 11.1 Introduction
 11.2 Synthetic Approaches to Organotrifluoroborates
 11.3 Elaboration of Organotrifluoroborates via Transformations of Pendant Functional Groups
 11.4 Transition Metal-Catalyzed Processes
 11.5 Miscellaneous Reactions of Organotrifluoroborates
 11.6 Carbon–Carbon Bond-Forming Reactions with Activated Electrophiles
 11.7 Conclusions

12 Borate and Boronic Acid Derivatives as Catalysts in Organic Synthesis
 Joshua N. Payette and Hisashi Yamamoto
 12.1 Introduction
 12.2 Nonchiral Boron-Based Catalysis
 12.3 Chiral Boron-Based Catalysis
 12.4 Conclusion

13 Applications of Boronic Acids in Chemical Biology and Medicinal Chemistry
 Nanting Ni and Binghe Wang
 13.1 Introduction
 13.2 Boronic Acids as Potential Medicinal Agents
 13.3 Probes for Detecting Reactive Oxygen Species
 13.4 MRI and PET Agents for in vivo Carbohydrate Imaging
 13.5 Carbohydrate Biomarker Binding Agents and Sensors
 13.6 Conclusions

14 Boronic Acids in Materials Chemistry
 Jie Liu and John J. Lavigne
 14.1 Introduction
 14.2 Linear Boronate-Linked Materials
 14.3 Macrocycles and Cages
 14.4 Networks
 14.5 Summary and Outlook

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